Product ID:VALIANT (INCLUDING PHD & PHD-XT PHD-EXT),66
MSDS Date:01/12/1990
FSC:6520
NIIN:00D002977
MSDS Number: BPZPX

CAULK/DENTSPLY

LAKEVIEW AND CLARKE AVE
MILFORD, DE 19963-0359
US

Emergency Phone: 302-422-4511

Info Phone: 302-422-4511/800-532-2855

Cage: 11107

CAULK/DENTSPLY

359 MILFORD, DE 19963-0359 US

Telephone: 302-422-4511/ 703-451-1900

Cage: 11107

SILVER (SARA III)

CAS: 7440-22-4

RTECS: VW3500000

OSHA PEL 0.01 MG/M3

ACGIH TLV: 0.1 MG/M3; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

COPPER (SARA III)

CAS: 7440-50-8

RTECS: GL5325000

OSHA PEL 0.1MG/M3 FUME/1 DUST

ACGIH TLV: 0.2MG/M3 FUME; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TIN

CAS: 7440-31-5

RTECS: XP7320000

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9293

PALLADIUM

OSHA PEL 15 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

LD50 LC50 Mixture:TLV FOR SILVER IS 0.1 MG/M3.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE AND CHRONIC- PROLONGED OR
REPEATED SKIN CONTACT MAY CAUSE IRRITATION OR ALLERGIC REACTION.
PROLONGED EXCESSIVE EXPOSURE TO DUST, MIST OR FUMES MAY CONTRIBUTE
TO CHRONIC RESPIRATORY AILMENTS IF I NHALED. EYE CONTACT MAY CAUSE
IRRITATION, TEARING AND PAIN. INGESTION:UNLIKELY.
Effects of Overexposure:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE
IRRITATION OR ALLERGIC REACTION. PROLONGED EXCESSIVE EXPOSURE TO
DUST, MIST OR FUMES MAY CONTRIBUTE TO CHRONIC RESPIRATORY AILMENTS
IF INHALED. EYE CONTACT MAY CAUSE IRRITATION, TEARING AND PAIN.
INGESTION:UNLIKELY.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE
MORE SUSCEPTIBLE TO THIS MATERIAL.

First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH
SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS
OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED.
ORAL:UNLIK ELY.

Extinguishing Media:USE DRY POWDER EXTINGUISHING AGENT.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN THE
POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:METAL POWDER IN AIR MAY CAUSE FIRE AND
EXPLOSION HAZARD. MOLTEN METAL CAN IGNITE COMBUSTIBLES.

Spill Release Procedures:VENTIALTE AREA. PICK UP POWDER SPILLS BY
METHODS SUCH AS VACUUMING OR WET MOPPING. PREVENT DUSTY CONDITIONS.

Handling and Storage Precautions:STORAGE- FOLLOW GOOD HOUSEKEEPING
PRACTICES AND GOOD INDUSTRIAL HYGIENE IN HANDLING THIS MATERIAL.
Other Precautions:OPERATIONS GENERATING AIRBORNE METAL DUST EXPOSURE
SUCH AS WELDING, MELTING, DRILLING ETC.. SHOULD BE PERFORMED WITH
VENTILATION.

Respiratory Protection:NIOSH APPROVED RESPIRATORS ARE REQUIRED WHEN
CONCENTRATIONS OF DUST AND/OR FUMES EXCEED TLV.
Ventilation:LOCAL
Protective Gloves:LEATHER OR RUBBER
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:RUBBER APRON, EYE WASH FOUNTAIN, EMERGECY
SHOWER
Work Hygienic Practices:OBSERVE NORMAL CARE WHEN WORKING WITH
CHEMICALS. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
DRINKING.
Supplemental Safety and Health

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:968F,520C
Spec Gravity:9.60
Solubility in Water:NOT SOLUBLE
Appearance and Odor:METALLIC GREY POWDER

Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS
Stability Condition to Avoid:CONTACT WITH MINERAL ACIDS WILL RELEASE
HYDROGEN, A DANGEROUS GAS.
Hazardous Decomposition Products:NONE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.